Experiments upon magnesia alba, quick-lime, and other alcaline substances / by Joseph Black.

  • Black Joseph, 1728-1799.
Date:
1893
Catalogue details

Licence: Public Domain Mark

Credit: Experiments upon magnesia alba, quick-lime, and other alcaline substances / by Joseph Black. Source: Wellcome Collection.

Provider: This material has been provided by the Royal College of Physicians of Edinburgh. The original may be consulted at the Royal College of Physicians of Edinburgh.

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    dissolved in a sufficient quantity of spirit of vitriol, and then again separated from the acid by the addition of an alkali, of which a large quantity is necessary for this purpose. The magnesia being very well washed and dried, weighed one dram and fifty grains. It effervesced violently, or emitted a large quantity of air, when thrown into acids; formed a red powder, when mixed with a solution of subhmate; separated the calcareous earths from an acid, and sweetened lime-water : and had thus recovered all those properties which it had but just now lost by calcination. Nor had it only recovered its original properties, but acquired besides an addition of weight, nearly equal to what had been lost in the fire ; and as it is found to effervesce with acids, part of the addition must certainly be air. This air seems to have been furnished by the alkali, from which it was separated by the acid; for Dr Hales has clearly proved, that alkaline salts contain a large quantity of fixed air, which they emit in great abundance when joined to a pure acid. In the present case, the alkali is really joined to an acid, but without any visible emission of air : and yet the air is not retained in it; for the neutral salt, into which it is converted, is the same in quantity, and in every other respect, as if the acid employed had not been previously saturated with magnesia, but offered to the alkali in its pure state, and had driven the air out of it in their conflict. It seems therefore evident, that the air was forced from the alkali by the acid, and lodged itself in the magnesia. These considerations led me to try a few experiments, whereby I might know what quantity of air is expelled from an alkali, or from tnagnesia, by acids. Two drams of a pure fixed alkaline salt, and an ounce of water, were put into a Florentine flask, which, together with its contents, weighed two ounces and two drams. B