The liquefaction of gases : papers / by Michael Faraday, (1823-1845) ; with an appendix consisting of papers by Thomas Northmore on the compression of gases. (1805-1806).

  • Faraday, Michael, 1791-1867.
Date:
1904
Catalogue details

Licence: In copyright

Credit: The liquefaction of gases : papers / by Michael Faraday, (1823-1845) ; with an appendix consisting of papers by Thomas Northmore on the compression of gases. (1805-1806). Source: Wellcome Collection.

Provider: This material has been provided by UCL Library Services. The original may be consulted at UCL (University College London)

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    densed, and in all its characters was like that prepared by the former process. A small gage was attached to a tube in which sul- phurous acid was afterwards formed, and at a temperature of 45° F. the pressure within the tube was equal to three atmospheres, there being a portion of liquid sulphurous acid present: but as the common air had not been ex- cluded when the tube was sealed, nearly one atmosphere must be due to its presence, so that sulphurous acid vapour exerts a pressure of about two atmospheres at 45° F. Its specific gravity was nearly 1.42.* Sulphuretted hydrogen. A tube being bent, and sealed at the shorter end, strong muriatic acid was poured in through a small funnel, so as nearly to fill the short leg without soiling the long one. A piece of platinum foil was then crumpled up and pushed in, and upon that were put fragments of * I am indebted to Mr. Davies Gilbert, who examined with much attention the results of these experiments, for the suggestion of the means adopted to obtain the specific gravity of some of these fluids. A number of small glass bulbs were blown and hermeticall}' sealed ; they were then thrown into alcohol, water, sulphuric acid, or mix- tures of these, and when any one was found of the same specific gravity as the fluid in which it was immersed, the specific gravity of the fluid was taken : thus a number of hydrometrical bulbs were obtained; these were introduced into the tubes in which the sub- stances were to be liberated; and ultimately, the dry liquids ob- tained, in contact with them. It was then observed whether they floated or not, and a second set of experiments were made with bulbs lighter or heavier as required, until a near approximation was obtained. Many of the tubes burst in the experiments, and in others difficulties occurred from the accidental fouling of the bulb by the contents of the tube. One source of error may be mentioned in addition to those which are obvious, namely, the alteration of the bulk of the bulb by its submission to the pressure required to keep the substance in the fluid state.