The liquefaction of gases : papers / by Michael Faraday.

Date:
1896
Catalogue details

Licence: Public Domain Mark

Credit: The liquefaction of gases : papers / by Michael Faraday. Source: Wellcome Collection.

Provider: This material has been provided by the Royal College of Physicians of Edinburgh. The original may be consulted at the Royal College of Physicians of Edinburgh.

    19/90 (page 13)
    sulphuret of iron, until the tube was nearly full. In this way action was prevented until the tube was sealed. If it once commences, it is almost impossible to close the tube in a manner sufficiently strong, because of the pressing out of the gas. When closed, the muriatic acid was made to run on to the sulphuret of iron, and then left for a day or two. At the end of that time, much proto-muriate of iron had formed, and on placing the clean end of the tube in a mixture of ice and salt, warming the other end if necessary by a little water, sulphuretted hydrogen in the liquid state distilled over. The liquid sulphuretted hydrogen was colourless, limpid, and excessively fluid. Ether, when compared with it in similar tubes, appeared tenacious and oily. It did not mix with the rest of the fluid in the tube, which was no doubt saturated, but remained standing on it. When a tube containing it was opened, the liquid im- mediately rushed into vapour; and this being done under water, and the vapour collected and examined, it proved to be sulphuretted hydrogen gas. As the temperature of a tube containing some of it rose from 0° to 45°, part of the fluid rose in vapour, and its bulk diminished; but there was no other change : it did not seem more adhesive at 0° than at 45°. Its refractive power appeared to be rather greater than that of water ; it decidedly surpassed that of sulphurous acid. A small gage being introduced into a tube in which liquid sulphuretted hydrogen was afterwards produced, it was found that the pressure of its vapour was nearly equal to 17 atmospheres at the temperature of 50°. The gages used were made by drawing out some tubes at the blow-pipe table until they were capillary, and of a trumpet form; they were graduated by bringing a small portion of mercury successively into their different parts ; they were then sealed at the fine end, and a portion of